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These results unambiguously locate the photosensitive azobenzene ligands, along with surfactant, within the uniform nanopores of the self-assembled lms and emphasize the need to accommodate the steric demands of the photoisomerization process by engineering the pore size (as noted previously for adsorbed azobenzene dyes (Ogawa et al, 2000)) and positioning the photoactive species on the pore surfaces Correspondingly, nanocomposite lms prepared using the triblock copolymer surfactant P123, which had larger pores (ca 65 nm in diameter), exhibited a faster and more complete trans-cis isomerization, close to that of TSUA in EtOH solution, presumably because the azobenzene ligands were less sterically constrained It is noteworthy that there exists a difference between the UV/visible spectra of Brij 56 templated nanocomposite lms before (Fig 1312a) and after (Fig 1312b) the surfactant removal.

whole thing from there. Theme option pages have been around for quite some time, and the default WordPress theme uses the technique to offer color customizations to the rounded header, along with other things. What you want your theme options page to do, if you feel you need one, depends on the kind of theme you ve built. Some themes let the user alter the design by changing default font sizes and things like that, while others let you save custom code that will be output somewhere in the theme through action hooks. Either way, you should make sure you know why you may want an options page, and what you need it to do.

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For the azobenzene contained in the nanocomposite lm before the surfactant removal, the p p* transition of the trans isomer is at 333 nm and the n p* transition of the cis isomer is at 440 nm After the surfactant removal, the p p* transition of the trans isomer and the n p* transition of the cis isomer are shifted to 350 and 460 nm, respectively In both situations, the absorbance of the n p* transition is quite high, indicating that the molar absorption coef cient (e) of the n p* transition is larger than that in solution owing to the out-of-plane position of the azobenzene phenyl rings This effect may be the result of steric constraint and hydrogen-bonding interactions between the azo- and silanol groups on the silica wall.

(Originally published on Mediapost.com) A funny thing happened on the way to the CMO s of ce. Between the realization of an eye-opening, gamechanging insight gleaned from advertising test results and web behavior data, the report you were gleefully ferrying to the C-Suite wilted, turned brown at the edges and started to dribble a slimy substance with a conspicuous stench. The CMO immediately developed a nose-squint. The VP of Corporate Communications had that Oooo, you re in for it! look in her eye and the VP of Advertising nudged the Director of Direct Marketing and said sotto-voce, The golden boy is about to nd out his day in the sun has turned him to toast. The CMO pointed to (but did not touch): A traf c report from comScore A traf c report from Hitwise

In comparison to the azobenzene contained in the nanocomposite lm after the surfactant removal, the appearance of the p p* and the n p* transitions at lower wavelength (blueshift) before the surfactant removal indicates that the azobenzene ligands are out of plane to a larger extent The absorbance at the n p* transition of azobenzene ligands contained in P123-templated lm is lower than that in the Brij 56 templated lm, indicating a less sterically constrained environment because of the larger pore sizes of P123-templated lm The preceding UV/visible data were measured using a re ection mode For TSUA-modi ed nanocomposite thin lms coated on indium tin oxide (ITO)/glass substrates, a transmission mode was adopted to measure the absorbance of the lms In the experiment, the lm was soaked in a Tris buffer solution containing.

The admin options pages can more or less be used to do just about anything. You kick it off in functions.php, but then you can call other files or just put the whole thing there. Keep it somewhat sane, though, since functions.php is part of your theme and it may slow things down if you cram it too full of cool functionality that needs to run a ton of things at once. As an example we ll take a look at the Notes Blog Core placeholder page, output by functions.php just to say hi, more or less. First of all, you need to add the menu item to the WordPress admin. That means you need to add an action, and define the theme s option page: 129

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